Iron promoted conjugate addition: implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate.
نویسندگان
چکیده
Treatment of (η(1)-mesityl)(2)Fe(κ(2)-TMEDA) (1') with an α,β-unsaturated carbonyl compound results in 1,4-addition of the mesityl group to give an iron enolate quantitatively. The Z-configuration of the enolate suggested the six-centered mechanism for the conjugate addition.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 100 شماره
صفحات -
تاریخ انتشار 2012